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TDPAC study of indium oxide

Identifieur interne : 000743 ( Main/Exploration ); précédent : 000742; suivant : 000744

TDPAC study of indium oxide

Auteurs : RBID : ISTEX:10751_1983_Article_BF02159787.pdf

Abstract

TDPAC measurements on polycristalline indium oxide powder using the well known 174–245 keV cascade of111In were performed at different temperatures. In accordance with X-ray diffraction data,111In was observed in two sites which are clearly distinguishable by the coordinations of the nearest neighbor oxygen ions. A calculation of the ionic electric field gradient produced by these gave fair agreement with the experimental ratio of the two field gradients, the asymmetry parameters and the relative fraction of In ions at both sites. The observed quadrupole interaction parameters are very similar to the ones found in the internal oxidation of In in Ag and AgIn alloys.

DOI: 10.1007/BF02159787

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Le document en format XML

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<div type="abstract" xml:lang="eng">TDPAC measurements on polycristalline indium oxide powder using the well known 174–245 keV cascade of111In were performed at different temperatures. In accordance with X-ray diffraction data,111In was observed in two sites which are clearly distinguishable by the coordinations of the nearest neighbor oxygen ions. A calculation of the ionic electric field gradient produced by these gave fair agreement with the experimental ratio of the two field gradients, the asymmetry parameters and the relative fraction of In ions at both sites. The observed quadrupole interaction parameters are very similar to the ones found in the internal oxidation of In in Ag and AgIn alloys.</div>
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<abstract lang="eng">TDPAC measurements on polycristalline indium oxide powder using the well known 174–245 keV cascade of111In were performed at different temperatures. In accordance with X-ray diffraction data,111In was observed in two sites which are clearly distinguishable by the coordinations of the nearest neighbor oxygen ions. A calculation of the ionic electric field gradient produced by these gave fair agreement with the experimental ratio of the two field gradients, the asymmetry parameters and the relative fraction of In ions at both sites. The observed quadrupole interaction parameters are very similar to the ones found in the internal oxidation of In in Ag and AgIn alloys.</abstract>
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